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The episode that got me hooked was the one about a phantom arm. A man no longer had his arm (I forgot how he lost it, the military?) and for several years had severe (phantom) pain coming from where his arm once was. He said it felt like his fist was clinched tightly and like his nails were digging into the palm of his hand. It was all psychological. He visited several doctors for many years and no one was able to cure his pain... since there wasn't any arm to treat. Finally the man went to see a new doctor (with a Eastern European accent, it seems appropriate, doesn't it?) who McGyver'd up a mirror that created the illusion that he had his real arm. The doctor instructed him to move the hand on his real arm (that looked like his phantom arm while looking into the mirror) as if he was un-clinching his fist. After several weeks of doing this, he no longer felt any pain in his phantom arm! Cool, huh?
I know, I didn't do a very good job of explaining the story. You're just going to have to check it out yourself. Along with some other Radio Lab podcasts. I think you're going to heart it too. :)